What is the Difference Between Nitrobenzene and Aniline?
🆚 Go to Comparative Table 🆚Nitrobenzene and aniline are both aromatic organic compounds, but they have distinct differences in their structure and properties. The main difference between the two is the substituent group attached to the benzene ring:
- Nitrobenzene: This compound has a nitro group (-NO2) attached to the benzene ring. It is an organic compound with the chemical formula C6H5NO2. Nitrobenzene is a pale yellow to dark brown liquid and is used in the production of aniline.
- Aniline: This compound has an amino group (-NH2) attached to the benzene ring. It is an aromatic organic compound with the chemical formula C6H5NH2. Aniline is an oily liquid that can be colorless to brown and is useful as a precursor to urethane rubber chemicals, pesticides, dyes, explosives, and pharmaceuticals.
In addition to the structural differences, nitrobenzene and aniline have different chemical properties. For example, aniline, being a primary aromatic amine, gives carbylamine and azo dye tests, while nitrobenzene does not. On the other hand, nitrobenzene gives the Barker-Mulliken test, which is not given by aniline.
Comparative Table: Nitrobenzene vs Aniline
Here is a table comparing the differences between nitrobenzene and aniline:
Property | Nitrobenzene | Aniline |
---|---|---|
Chemical Formula | C6H5NO2 | C6H5NH2 |
Substituent | Nitro group (-NO2) | Amine group (-NH2) |
Color | Pale yellow to dark brown liquid | Colorless to brown oily liquid |
Odor | Almond-like | - |
Reactivity | Nitro group is a strong electron-withdrawing group, making it less basic than aniline | Aniline is more basic than nitrobenzene |
Uses | Primarily used as a precursor for aniline production | Useful as a precursor to urethane rubber chemicals, pesticides, dyes, explosives, and pharmaceuticals |
The key difference between nitrobenzene and aniline is the substituent attached to the benzene ring. Nitrobenzene has a nitro group (-NO2), while aniline has an amine group (-NH2).
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