What is the Difference Between Hydrazine and Carbohydrazide?

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The main difference between hydrazine and carbohydrazide lies in their chemical structures. Hydrazine contains an H2N-NH2 structure, whereas carbohydrazide has two hydrazine molecules attached to a single carbonyl carbon center. Here are some key points about both compounds:

  • Hydrazine: It is a colorless liquid and an inorganic compound. Hydrazine is used as a reagent in organic synthesis and to develop munitions propellants.
  • Carbohydrazide: Also known as Carbodihydrazide, it is a white, water-soluble solid that decomposes at a melting point of about 153°C. Carbohydrazide is a chemical compound with the formula OC(N2H3)2. It is used as an oxygen scrubber, precursor to polymers, and in photography as a stabilizer.

Both hydrazine and carbohydrazide are nitrogen-containing compounds, but they differ in their applications and safety aspects. Hydrazine has been largely replaced by carbohydrazide as an oxygen scavenger due to safety and health concerns. Carbohydrazide is considered a safer alternative to hydrazine, as it does not cause the same difficulties in handling.

Comparative Table: Hydrazine vs Carbohydrazide

Hydrazine and carbohydrazide are nitrogen-containing chemical compounds with different structures and properties. Here is a comparison table highlighting the key differences between them:

Property Hydrazine Carbohydrazide
Chemical Structure H2N-NH2 (H2N-NH)2C-NH-C(NH2)(H2N-NH2)
Appearance Colorless liquid White solid
Classification Inorganic compound Organic compound
Production Oxidation of ammonia via oxaziridines from peroxide, chlorine-based oxidations, etc. Treatment of urea with hydrazine
Boiling Point 113°C 153°C
Oxygen Scavenging Byproducts H2O and N2 H2O, N2 and urea

Hydrazine has an H2N-NH2 structure and is a colorless liquid, while carbohydrazide has a more complex structure with two hydrazine molecules attached to a single carbonyl carbon center and exists as a white solid. Hydrazine is classified as an inorganic compound, whereas carbohydrazide is an organic compound. Hydrazine is typically produced using oxidation of ammonia through various methods, and carbohydrazide is produced through the treatment of urea with hydrazine. Both compounds have been used as oxygen scavengers in boiler water treatment, but carbohydrazide has replaced hydrazine due to safety and health concerns. The byproducts of hydrazine and carbohydrazide in oxygen scavenging reactions are different, with hydrazine producing water and nitrogen, while carbohydrazide produces water, nitrogen, and urea.