What is the Difference Between Neoprene and Nitrile Rubber?

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Neoprene and nitrile rubber are both synthetic rubbers with similar properties, but they have distinct differences that make them suitable for different applications. Here are the main differences between neoprene and nitrile rubber:

  1. Chemical Composition: Neoprene is made from chloroprene, while nitrile rubber is produced from copolymers of butadiene and acrylonitrile.
  2. Physical Properties: Neoprene has a wider range of hardness (15 to 95 Shore A) compared to nitrile rubber (35 to 90 Shore A). Neoprene also has a higher elongation (100% to 800%) than nitrile rubber (400% to 600%).
  3. Resistance: Nitrile rubber is known for its superior chemical, abrasion, and temperature resistance. Neoprene, on the other hand, is valued for its resistance to weather and impact. Neoprene offers moderate resistance to oils and petroleum products but provides greater resistance to sunlight, ozone, and weather. Nitrile rubber has poor flame resistance, while neoprene provides very good-to-excellent resistance against the spread of flame.
  4. Manufacturing Methods: Neoprene is more commonly extruded, while nitrile is often molded due to its natural connection to the automotive industry.
  5. Cost: Nitrile rubber is generally more expensive than neoprene due to its added oil resistance.

Both materials are used in various industrial applications, but their specific properties make them more suitable for different uses. For example, nitrile rubber is ideal for applications involving constant exposure to oil, while neoprene is suitable for parts that encounter intermittent exposure to oil.

Comparative Table: Neoprene vs Nitrile Rubber

Here is a table comparing the differences between neoprene and nitrile rubber:

Property Nitrile Rubber Neoprene Rubber
Common Names Nitrile, Buna-N, NBR Neoprene
Chemical Names Acrylonitrile-butadiene Polychloroprene
ASTM D-2000 Classification BF, BG, BK, CH BC, BE
Elongation 400% to 600% 100% to 800%
Hardness (Shore A) 35 to 90 15 to 95
Compression Set Good Good
Rebound Rating Good Fair to Very Good
Flex Cracking Resistance Good Good to Very Good
Abrasion Resistance Good to Excellent Very Good to Excellent
Tear Resistance Good Good
Impact Resistance Fair to Good Good to Excellent
Flame Resistance Poor Very Good to Excellent
Minimum Service Temperature -40°C -40°C
Maximum Service Temperature 149°C 121°C
Chemical Resistance Generally resistant to gases, aliphatic hydrocarbons, oils, and fuels Moderate chemicals and acids, ozone, oils, fats, greases, and solvents
Generally Attacked By Ketones, ozone, sunlight, aromatic oil, flame, weather Esters, ketones, and chlorinated, aromatic, and nitro hydrocarbons

Nitrile rubber has better oil and chemical resistance, while neoprene has better physical properties and resistance against sunlight, ozone, and weather conditions. Both materials are highly oil-resistant, but nitrile is the better choice when an application involves an excessive amount of oil. Neoprene offers moderate resistance to oils and petroleum products and provides significantly greater resistance to sunlight, ozone, and weather. In contrast, nitrile rubber is attacked by sunlight, ozone, and weather.