What is the Difference Between Surface Tension and Viscosity?

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Surface tension and viscosity are both properties of fluids that depend on intermolecular forces, but they have different characteristics and effects on liquids.

Surface Tension:

  • Surface tension is the amount of energy required to increase the surface area of a liquid by a unit area.
  • It is the property of a liquid surface that resists force, serving as a barrier to foreign materials and keeping the liquid molecules bound together.
  • Surface tension is determined by the difference in interactions between the molecules of the material (fluid) with the molecules of the material in contact.
  • It is mostly stable and changes primarily due to temperature and chemicals that modify the bonding characteristics of the molecules.

Viscosity:

  • Viscosity is the resistance of a fluid to flow.
  • It results from the collaboration among molecules of identical molecules located in the same material (in the case of fluids).
  • Viscosity is related to the friction between molecules in a fluid, which causes the resistance to deformation or movement.
  • It varies depending on shear rate and is influenced by factors such as temperature and the presence of surface-active agents like surfactants.

While there is a common belief that high viscosity fluids should have high surface tension, this correlation is not accurate. In fact, high viscosity does not necessarily imply high surface tension, as seen in substances like glue.

Comparative Table: Surface Tension vs Viscosity

Here is a table comparing surface tension and viscosity:

Property Surface Tension Viscosity
Definition Surface tension is the force parallel to the surface perpendicular to a unit length line, measured in N/m or J/m². Viscosity is a measure of a fluid's resistance to flow, or its internal friction, typically measured in Pa·s or centipoise (cP).
Occurrence Present in both moving and nonmoving fluids. Appears only in moving fluids.
Factors Affecting Surface tension is affected by the unbalanced intermolecular forces at the surface of a liquid. Viscosity is affected by factors such as temperature and the presence of chemical additives.
Examples Water striders use the surface tension of water to stand on its surface. High viscosity liquids may have low surface tension, such as wood glue, enabling it to penetrate irregular wood surfaces.

In summary, surface tension is a property related to the behavior of the surface of a liquid, while viscosity is about the resistance to flow within the bulk of a liquid. These properties are different and have distinct characteristics.